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meso-Aryl substituted stable unorthodox 5,10-porphodimethenes with α,β and β,β-Nmethyl pyrrole connectivities: synthesis and spectroscopic, solid state and theoretical characterization.

Nyancy, Halder and Sangeetha, Mohandas and Usharani, D. and Harapriya, Rath (2019) meso-Aryl substituted stable unorthodox 5,10-porphodimethenes with α,β and β,β-Nmethyl pyrrole connectivities: synthesis and spectroscopic, solid state and theoretical characterization. Organic and Biomolecular Chemistry, 17. pp. 6131-6135.

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Abstract

A concise and convenient synthetic methodology leading to an unambiguous isolation of two hitherto unknown highly stable single conformers of meso-aryl substituted unorthodox 5,10-porphodimethenes has been developed by the inclusion of N-methyl pyrrole units with α,β and β,β-linkages into the core of heterocyclic macrocycles.

Item Type: Article
Uncontrolled Keywords: Porphyrins, porphyrin analogues, N-methyl pyrrole
Subjects: 500 Natural Sciences and Mathematics > 04 Chemistry and Allied Sciences > 24 Organic Chemistry
Divisions: Food Safety Analytical Quality Control Lab
Depositing User: Food Sci. & Technol. Information Services
Date Deposited: 25 Nov 2020 09:20
Last Modified: 25 Nov 2020 09:20
URI: http://ir.cftri.com/id/eprint/14641

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