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Infrared spectroscopic study of the structural transitions of C60Br24

Resmi, M.R. and George, L. and Singh, S. and Pradeep, T. and Udaya Sankar, K. (1997) Infrared spectroscopic study of the structural transitions of C60Br24. Journal of Molecular Structure, 435. pp. 11-15.

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Variable temperature infrared spectroscopy and differential scanning calorimetry measurements show that C60Br24 under-goes two structural transitions at 171 and 180 K with AH values of 0.87 and 3.94 kJ mol-1 respectively. Only one transition is clearly visible in IR which is manifested by the hardening of certain IR peaks and narrowing of the 1400 cm-1 transition. The results support an orientational change although ordering of the solvated bromine molecules could also be a reason for the observed changes.

Item Type: Article
Uncontrolled Keywords: Infrared spectroscopy; C60Br24; Structural transitions
Subjects: 500 Natural Sciences and Mathematics > 04 Chemistry and Allied Sciences > 10 Spectroscopic and Spectrometric analysis
Divisions: Food Engineering
Depositing User: Food Sci. & Technol. Information Services
Date Deposited: 04 Jul 2007 08:55
Last Modified: 28 Dec 2011 09:28
URI: http://ir.cftri.com/id/eprint/1287

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