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A Convenient Practical Synthesis of Alkyl and Aryl Oxime Esters.

Santosh Kumar, S. C. and Vijendra Kumar, N. and Srinivas, P. and Bettadaiah, B. K. (2014) A Convenient Practical Synthesis of Alkyl and Aryl Oxime Esters. Synthesis, 46. pp. 1847-1852.

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Abstract

A facile access to the synthesis of alkyl and aryl oxime esters of ketoximes and aldoximes in high yields (90–97%) is reported. The reactions were performed using N-[3-(methylamino)propyl]-N′-ethylcarbodiimide hydrochloride (EDCI) reagent in the presence of 4- (dimethylamino)pyridine (DMAP) as a catalyst at room temperature. The isolation and purification of products is very simple and in cases where product is solid, column chromatography is avoided.

Item Type: Article
Uncontrolled Keywords: oxime esters, aldoximes, ketoximes, EDCI, esterification, dehydration
Subjects: 500 Natural Sciences and Mathematics > 04 Chemistry and Allied Sciences > 24 Organic Chemistry
Divisions: Plantation Products Spices and Flavour Technology
Depositing User: Food Sci. & Technol. Information Services
Date Deposited: 07 Nov 2016 07:39
Last Modified: 07 Nov 2016 07:39
URI: http://ir.cftri.com/id/eprint/12393

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