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Znbr2-Catalyzed and Microwave-Assisted Synthesis of 2,3-Unsaturated Glucosides Of Hindered Phenols and Alcohols.

James Bound, D. and Bettadaiah, B. K. and Srinivas, P. (2014) Znbr2-Catalyzed and Microwave-Assisted Synthesis of 2,3-Unsaturated Glucosides Of Hindered Phenols and Alcohols. Synthetic Communications, 44. pp. 2565-2576.

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Abstract

Zinc bromide (ZnBr2) under microwave irradiation efficiently catalyzed the Ferrier reaction of hindered phenols and alcohols to afford the corresponding a-2,3-unsaturated glucoside acetates in good yields and with good stereoselectivity. The reaction affords a facile access to new 2,3-dideoxyglucosides of important phenolic and alcoholic constituents of spices.

Item Type: Article
Uncontrolled Keywords: Alcohols; Ferrier reaction; microwave; phenols; 2,3-unsaturated 1-O-glucosides; ZnBr2
Subjects: 500 Natural Sciences and Mathematics > 04 Chemistry and Allied Sciences > 24 Organic Chemistry
Divisions: Plantation Products Spices and Flavour Technology
Depositing User: Food Sci. & Technol. Information Services
Date Deposited: 26 Sep 2014 07:21
Last Modified: 26 Sep 2014 07:21
URI: http://ir.cftri.com/id/eprint/11637

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